3. Black Widow: Marvel Comics-Tales of Suspense #52, 1964
Do not get trapped in the web of this black widow!

This lovely arachnid could offer up several unbeatable ways to kick your butt into next week! As an expert martial artist with focuses in judo, karate, ninjitsu, aikido, savate, boxing, and a kung fu or two; she will probably find it most difficult to figure out what move she will have most fun taking you out with. As well as being an expert at the above fighting techniques she is a world-class gymnast, acrobat, and aerialist. Oh, and as her Russian heritage would demand an accomplished ballerina.
Do not go signing up for karate just yet, Black Widow’s physical and mental abilities have been enhanced beyond human limits with the help of the Super-Soldier Serum. Also, as a result of biotechnological enhancements she does not age (every woman’s dream), is not susceptible to diseases and heals at a superhuman rate.
As one of the greatest spies ever, a member of S.H.I.E.L.D, and the Avengers this redhead finds herself at the #3 spot.
1 comment
You missed one! Firestar!
https://en.wikipedia.org/wiki/Firestar